ChemicalBook >> CAS DataBase List >>D(+)-Phenylalaninol
D(+)-Phenylalaninol
- CAS No.
- 5267-64-1
- Chemical Name:
- D(+)-Phenylalaninol
- Synonyms
- D-PHENYLALANINOL;H-D-PHE-OL;D-Phenylalanino;(R)-2-AMINO-3-PHENYL-1-PROPANOL;(2R)-2-amino-3-phenylpropan-1-ol;(R)-2-AMINO-3-PHENYL-PROPAN-1-OL;H-D-Phen-ol;R-228060-001;D-PHENYLANINOL;D-PHEYLALANINOL
- CBNumber:
- CB9741308
- Molecular Formula:
- C9H13NO
- Molecular Weight:
- 151.21
- MDL Number:
- MFCD00064298
- MOL File:
- 5267-64-1.mol
- MSDS File:
- SDS
Last updated:2023-08-18 13:05:06
| Melting point | 93-95 °C(lit.) |
|---|---|
| Boiling point | 122 °C / 4mmHg |
| alpha | 23 º (c=1.2, 1 N HCl 22 ºC) |
| Density | 1.0406 (rough estimate) |
| refractive index | 23.5 ° (C=1.2, 1mol/L HCl) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Soluble in Dichloromethane, Ethyl Acetate, Methanol. |
| form | Crystalline Powder and Chunks |
| pka | 12.85±0.10(Predicted) |
| color | White to yellow |
| optical activity | [α]/D +22.8°, c = 1.2 in 1 M HCl |
| Sensitive | Air Sensitive |
| BRN | 4665408 |
| InChI | InChI=1/C9H13NO/c10-9(7-11)6-8-4-2-1-3-5-8/h1-5,9,11H,6-7,10H2/t9-/s3 |
| InChIKey | STVVMTBJNDTZBF-DJEYLCQNNA-N |
| SMILES | C(C1C=CC=CC=1)[C@@H](N)CO |&1:7,r| |
| CAS DataBase Reference | 5267-64-1(CAS DataBase Reference) |
| FDA UNII | A6QY3U3O3V |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45-27 | |||||||||
| RIDADR | UN 3259 8/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-23 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29221990 | |||||||||
| NFPA 704 |
|
D(+)-Phenylalaninol price More Price(32)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 284491 | (R)-(+)-2-Amino-3-phenyl-1-propanol 98% | 5267-64-1 | 5g | $142 | 2023-01-07 | Buy |
| TCI Chemical | P1289 | D-Phenylalaninol >98.0%(GC)(T) | 5267-64-1 | 5g | $72 | 2023-06-20 | Buy |
| TCI Chemical | P1289 | D-Phenylalaninol >98.0%(GC)(T) | 5267-64-1 | 25g | $218 | 2023-06-20 | Buy |
| Alfa Aesar | L09697 | D-Phenylalaninol, 98% | 5267-64-1 | 1g | $44.6 | 2023-06-20 | Buy |
| Usbiological | 019430 | D-Phenylalaninol | 5267-64-1 | 5g | $403 | 2021-12-16 | Buy |
D(+)-Phenylalaninol Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powde
Uses
D-Phenylalaninol is used as a chiral auxiliary for asymmetric Michael reactions. It is an enantiomer of L-Phenylalaninol, an inhibitor of intestinal Phenylalanine absorption. It acts as an inhibiting agent to the enzymes which are responsible for the breakdown of endorphins.
Purification Methods
It can be recrystallised from Et2O, *C6H6/pet ether (b 40-60o) or toluene and distilled in a vacuum. It has been purified by dissolving in Et2O, drying over K2CO3, filtering, evaporating to a small volume, cooling in ice and collecting the plates. Store them in the presence of KOH (i.e. CO2—free atm). [Karrer & Ehrhardt Helv Chim Acta 34 3203 1951, Oeda Bull Chem Soc Jpn 13 465 1938.] The picrate has m 141-141.5o (from EtOH/pet ether). The hydrogen oxalate has m 177o, 161-162o [Hunt & McHale J Chem Soc 2073 1957]. The racemate has m 87-88o from *C6H6/pet ether (75-77o from Et2O), and the hydrochloride has m 139-141o [Fodor et al. J Chem Soc 1858 1951]. [Beilstein 13 IV 1920.]
D(+)-Phenylalaninol Preparation Products And Raw materials
Global( 491)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39917 | 58 |
| Zhengzhou Anbu Chem Co.,Ltd | +8615988602810 | sales@anbuchem.com | China | 2999 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | 15028179902 +8615028179902 | sales@hbmojin.com | China | 12320 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29767 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21719 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29920 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8835 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22970 | 58 |
View Lastest Price from D(+)-Phenylalaninol manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-08-18 | D(+)-Phenylalaninol
5267-64-1
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2023-07-26 | D(+)-Phenylalaninol
5267-64-1
|
US $0.00 / KG | 100g | 98%+ | 100kg | WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD | |
 |
2023-06-14 | D(+)-Phenylalaninol
5267-64-1
|
US $0.00 / KG | 0.1KG | 99% | 1000KGS | Zhengzhou Anbu Chem Co.,Ltd |
-
- D(+)-Phenylalaninol
5267-64-1
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- D(+)-Phenylalaninol
5267-64-1
- US $0.00 / KG
- 98%+
- WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD
-
- D(+)-Phenylalaninol
5267-64-1
- US $0.00 / KG
- 99%
- Zhengzhou Anbu Chem Co.,Ltd
5267-64-1(D(+)-Phenylalaninol)Related Search:
D-(+)-Phenylalinol
S/R-Phenylalaninol
(2R)-2-amino-3-phenylpropan-1-ol
BENZENEPROPANOL, .BETA.-AMINO-, (.BETA.R)-
D-Penylalaninol
D-PHEYLALANINOL
D-PHENYLANINOL
(D)-(+)-2-PHENYLALANINOL / D-(+)-2-AMINO-3-PHENYL-1-PROPANOL
D-Phenylalaninol(R+Phenylalaninol)
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(αR)-α-(Hydroxymethyl)benzeneethanamine
H-D-Phen-ol
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(βR)-β-AMino-benzenepropanol
D-Phenylalaninol, (2R)-2-Amino-1-hydroxy-3-phenylpropane
BENZENEPROPANOL, B-AMINO-, (BR)-
D-(R)-PHENYLALANINOL
(+)-D-PHENYLALANINOL
D(+)-PHENYLALANINOL
D-PHENYLALANINOL
D-ALPHA-PHENYLALANINOL
D(+)-2-AMINO-3-PHENYL-1-PROPANOL
D-2-PHENYLALANINOL
H-D-PHE-OL
H-D-PHENYLALANINOL
(R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL
(R)-2-AMINO-3-PHENYL-1-PROPANOL
(R)-2-AMINO-3-PHENYL-PROPAN-1-OL
(R)-(+)-PHENYLALANINOL
(R)-PHENYLALANINOL
PHENYLALANINOL-D
(R)-2-amino-3-phenylpropanol
(R)-2-Amino-3-phenyl-1-propanol
D(+)-Phenylalaninol
D(+)-2-Amino-3-phenyl-1-propanol
D-2-Amino-3-phenyl-1-propanol,99%e.e.
R-228060-001
(R)-(+)-2-Amino-3-phenyl-1-propanol 98%
D-Phenylalaninol>
Benzenepropanol, β-amino-, (βR)-
D-Phenylalanino
D(+)-Phenylalaninol USP/EP/BP
D-(+)-2-Amino-3-phenyl-1-proanol
(+)-D-Phenylalaninol
5267-64-1
15267-64-1
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Asymmetric Synthesis
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